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Central Columbia Plateau - Yakima River Basin NAWQA Study - Publications


Agricultural Pesticides Found in Ground Water of the Quincy and Pasco Basins

Fact Sheet 240-95, Revised

Most commonly detected compounds (table)
Pesticides most heavily applied to some of the top cash row crops in the study area were detected in ground water.
Major row crops in the study area (table)
Major pesticides used on row crops in the study area (table)
Concentrations and detection frequencies of compounds in ground water (table)


ground-water pesticide sampling results: 15 wells had no detections, 30 wells had detections with concentrations less than human health criteria, 4 wells had detections with concentrations greater than human health criteria.90K

Most commonly detected compounds1 (table)

			Percentage of	Maximum
			wells with	concentra-
Compound		detections	tion(ug/L)2
--------		------------	-----------
Atrazine		    45	  	   0.97
Desethylatrazine	    37	  	   0.12
Simazine		    12	  	   0.011
1,2-dichloropropane	    12	  	   0.5
Metribuzin		    10	  	   0.028
Metolachlor		    10	  	   0.009
1,2,2-trichloropropane	     8	  	   0.55
EDB(1,2-dibromoethane)	     7	  	   1.1
1,2,3-trichloropropane	     6	  	   1.0
EPTC	  		     6	  	   0.012
Alachlor		     6	  	   0.008

1 Detected in more than 5 percent of samples
2 Micrograms per liter, or parts per billion (ppb)

Pesticides most heavily applied to some of the top cash row crops in the study area were detected in ground water.

Herbicides:

2,4-D (the most heavily applied pesticide for wheat) was detected at low concentrations in two wells. EPTC (the most heavily applied pesticide for alfalfa and other hay) was detected at low concentrations in three wells. Atrazine was the most frequently detected pesticide despite its low agricultural usage rate in the study area. Desethylatrazine (a degradation product of atrazine) was the second most frequently detected compound.

Fumigants:

1,3-dichloropropene (the most heavily applied pesticide for potatoes) was not detected. However, compounds were detected that were included either as active ingredients or as manufacturing by-products in early formulations of 1,3-dichloropropene-based fumigants. The active ingredient 1,2-dichloropropane, which was banned in 1976, was detected at low concentrations in six wells. The manufacturing by-products 1,2,3-trichloropropane (found in three wells), 1,3-dichloropropane (found in one well) and 1,2,2-trichloropropane (found in four wells) were detected at low concentrations. These compounds may be present in current 1,3-dichloropropene formulations at very low concentrations. EDB, another discontinued fumigant, was found in three wells at concentrations ranging from just below the MCL to over 20 times the MCL; more detections of EDB below the MCL (0.05mg/L) would be expected if the detection level were lower than the current value of 0.04 mg/L.


Major row crops in the study area (table)

				Estimated 	1994
				total		State
		Estimated	pesticides	cash
		acres		applied		value		Most heavily
Crop		cultivated	(tons/yr)	rank1		applied pesticide2
----		----------	----------	-----		-----------------
Wheat	  	  94,500	     40		  4		2,4-D
Potatoes	  59,800	  4,693		  5		1,3-dichloropropene4
Hay3	         149,100	     50	          7		EPTC
Onions	    	   3,900	     12		 14		DCPA
Asparagus	  12,900	     39		 16		Chlorpyrifos
Sweet Corn	  17,600	     25		 17		Alachlor
Feed Corn	  56,100	     34		 18		EPTC
Mint 	  	  10,600	     54		 19		Sulfur5
Barley	    	   6,400	      2		 25		Triallate
Carrots	    	   2,800	    161		 26		1,3-dichloropropene4

1Washington Agricultural Statistics Service [1995], Washington Agricultural Statistics 1994-1995, p.6
2Compounds in bold were detected in ground water
3Sum of alfalfa hay and other hay
4Volatile compounds present in early formulations of this nematocide were detected; see below
5Not targeted for analysis

Major pesticides used on row crops in the study area (table)

[I, insecticide; H, herbicide; F, fungicide; O, other; Ah, alfalfa hay; A,
asparagus; C, carrots; Cs, carrot seed; Co, feed corn; B, dry beans; G,
grapes; M, mint; On, onions; Po, potatoes; R, radish seed; Sc, sweet corn;
W, wheat; N, not detected; D, detected; --, not analyzed for]

Estimated amount Major applied1 target Sample Pesticide Type (tons/yr) crops result --------- ---- --------- ----- ------ 1,3-dichloropropene O 2,247 Po,C N Metam Sodium O 1,758 Po -- Sulfuric Acid O 525 Po -- Chloropicrin O 169 Po -- Maleic Hydrazide O 17 Po,On -- --------------------------------------------------------------------- Methamidophos I 37 Po -- Propargite I 36 Po,M,B N Disulfoton I 36 Po,A,R N Phorate I 33 Po N Ethoprop I 22 Po,Sc N Chlorpyrifos I 17 A,Sc,Ah N --------------------------------------------------------------------- EPTC H 78 Ah,Po,B D Metribuzin H 21 Po,Ah,A D 2,4-D H 17 W,Co,A D Alachlor H 16 Sc,B,Co D Diuron H 12 W,A,G D DCPA H 12 On,R,Cs N --------------------------------------------------------------------- Sulfur F 35 Po,M,G -- Mancozeb F 31 Po,A,On -- Chlorothalonil F 21 Po,C,On N --------------------------------------------------------------------- 1 Amount of active ingredient (based on information from Anderson, J.E. and Gianessi, L.,1995, Pesticide use in the Central Columbia Plateau; National Center for Food and Agricultural Policy).


Concentrations and detection frequencies of compounds in ground water (table)


Displays the table in-line in your browser as text. The table has 9 columns and 24 rows, plus notes. It includes data on herbicides, insecticides, degradation products, and fumigants and associated compounds. Displays the table in-line
in your browser as text. The table has 9 columns and 24 rows, plus notes. It
includes data on herbicides, insecticides, degradation products, and
fumigants and associated compounds.

In June 1996 the USGS National Water Quality Laboratory completed adjustments to the pesticide data base from schedules 2001/2010 and 2050/2051 covering sample dates from 1992 through February 29, 1996. Corrected method detection limits (MDLs) were assigned to nondetect values and E (estimate) codes were assigned more consistently. Also, all dimethoate values were deleted from the data base due to this compound's poor performance in analytical tests. While making these adjustments to the data base, it was discovered that some compounds detected at very low concentrations had been inadvertently reported as nondetections. These are now reported as detections. This most frequently occurred for desethylatrazine, simazine, and dieldrin.

Fact Sheet 240-95, Revised
Prepared by Lonna M. Roberts and Joseph L. Jones
July 1996


U.S. DEPARTMENT OF THE INTERIOR
U.S. GEOLOGICAL SURVEY
National Water-Quality Assessment Program

For further information contact:
Project Chief
CCYK NAWQA
1201 Pacific Ave., Suite 600
Tacoma, WA 98402
Phone:(253) 593-6510 ext2687; -6514 fax
Email: rwblack@usgs.gov

Suggested citation:
Roberts, L.M. and Jones, J.L., 1996, Agricultural Pesticides Found in Ground Water of the Quincy and Pasco Basins: U.S. Geological Survey Fact Sheet 240-95, on-line at <URL: https://wa.water.usgs.gov/ccyk/fs-240-95.html>, accessed October 17, 1997 .

For a paper copy of this report, send Email to: rwblack@usgs.gov


Central Columbia Plateau - Yakima River Basin NAWQA Study
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Last modified: Mon Oct 20 15:46:53 1997

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